29339900
ORGANIC CHEMICALS›Heterocyclic compounds with nitrogen hetero-atom(s) only
Other
Subcodes (3)
Scope and key substances of subheading 293399
CN subheading 293399 covers other heterocyclic compounds containing only nitrogen as the hetero-atom in the ring system, not classified in more specific subheadings of heading 2933. The most commercially significant substances include carbazole (CAS 86-74-8) - a tricyclic aromatic compound consisting of two benzene rings fused with a pyrrole ring, used as a raw material for dye synthesis, crop protection products, organic light-emitting diode (OLED) materials and photoconductors; acridine (CAS 260-94-6) - a tricyclic nitrogen-containing compound derived from anthracene, used as a precursor to acridine dyes and antiseptic agents and exploited in fluorescence diagnostics due to its strong DNA-intercalation properties; phenazine (CAS 92-82-0) - a diazanaphthalene ring system used in dye production and as a scaffold for synthesising antibiotics and anti-tumour compounds. Further substances classified here include indolizine, phenanthridine and their derivatives not covered by more specific subheadings. Carbazole is recovered primarily from coal tar fractions and is an important component of organic electronic materials. Acridine and its derivatives are used in cancer research and molecular biology as fluorescent intercalating agents. Classification under subheading 293399 requires the substance to be a chemically defined organic compound with a fused heterocyclic ring system containing at least one nitrogen atom and no heteroatoms of other elements.
REACH and CLP requirements for fused nitrogen heterocyclic compounds
Substances classified under subheading 293399 and imported into the EU are subject to REACH Regulation (EC) No 1907/2006. Importers bringing in more than one tonne per year must register the substance with the European Chemicals Agency (ECHA) or rely on a registration by the non-EU manufacturer's Only Representative. Carbazole is under evaluation for potential carcinogenic properties; certain carbazole derivatives may be subject to restrictions. Acridine is classified under CLP Regulation (EC) No 1272/2008 as toxic if swallowed and in contact with skin (H301, H311, H331) and causes serious eye damage (H318); its DNA-intercalating properties mean it is subject to genotoxicity screening. Phenazine is classified as toxic if swallowed or inhaled (H301, H331) and harmful to aquatic organisms. Safety Data Sheets (SDS) must be prepared in accordance with Annex II of Regulation (EU) 2020/878 and provided to professional recipients before the first delivery. Use of SVHC Candidate List substances above 0.1 % in articles triggers the obligation to provide information on safe use upon request from the recipient. Importers should monitor ECHA SVHC database updates, as polycyclic nitrogen-containing aromatic compounds are regularly assessed for CMR properties.
Customs procedures and import documentation for CN 293399
Importing goods under subheading 293399 requires filing an electronic customs declaration with the applicable CN or 8-digit TARIC code. Required documentation includes a commercial invoice stating the chemical name (IUPAC or trade name) and CAS number, a technical specification or certificate of analysis (CoA) confirming identity and purity, a transport document (CMR, AWB or bill of lading), a packing list and a Safety Data Sheet (SDS). Carbazole in solid form, acridine and phenazine may be transported as dangerous goods under ADR Class 6.1 (toxic substances) or Class 4.1 (flammable solids), depending on the specific CLP classification of the substance. Importers must verify current MFN tariff rates and any preferential rates available under EU free trade agreements in the TARIC database. For preferential rates, a valid proof of preferential origin - an EUR.1 movement certificate or an exporter's statement on the invoice - must be provided. Carbazole recovered from coal tar may require additional analysis for polycyclic aromatic hydrocarbon (PAH) contamination. Obtaining Binding Tariff Information (BTI) ruling is recommended where the classification of a specific substance is uncertain.
Chemical safety and SDS requirements
Organic substances under CN code 2933 99 (Other nitrogen-heteroatom heterocyclic compounds) require detailed chemical documentation for customs clearance. The Safety Data Sheet must comply with REACH Annex II. Substances classified as hazardous under CLP require GHS pictogram labelling. Transport follows ADR (road) or IMDG (maritime) regulations. Some organic substances may be subject to export controls as dual-use goods. Importers should verify whether the substance requires REACH authorisation (Annex XIV) or is subject to restrictions (Annex XVII).
Frequently asked questions
Is carbazole imported into the EU subject to REACH registration?
Yes. Carbazole (CAS 86-74-8) imported into the EU in quantities exceeding one tonne per year is subject to the registration obligation under REACH Regulation (EC) No 1907/2006. When sourced from coal tar fractions, the substance may be contaminated with polycyclic aromatic hydrocarbons (PAHs), which requires profiling the impurity content and considering the CLP classification of each relevant PAH. Importers should monitor the ECHA SVHC database for potential listing of carbazole or its derivatives as substances of very high concern.
What CLP classification applies to acridine under CN 293399?
Acridine (CAS 260-94-6) is classified under CLP Regulation (EC) No 1272/2008 as toxic if swallowed (H301), toxic in contact with skin (H311) and toxic if inhaled (H331). It causes serious eye damage (H318) and may cause skin sensitisation (H317). Packaging must bear GHS06 and GHS05 pictograms with appropriate H and P statements. An SDS in the relevant EU language is mandatory for professional recipients. Storage and handling require adequate ventilation and personal protective equipment.
What distinguishes CN 293399 substances from other subheadings of heading 2933?
Subheading 293399 is the residual subheading of heading 2933, covering nitrogen heterocyclic compounds not classified in more specific subheadings 293311 to 293395. The key criteria are that the ring system must contain only nitrogen as the heteroatom (no oxygen or sulphur), the structure must be fused aromatic, and the substance must not fall within a dedicated subheading such as pyridines (293339) or quinolines (293349). Where the classification of a specific substance is uncertain, the Explanatory Notes to heading 2933 should be consulted or Binding Tariff Information (BTI) ruling obtained.
How to classify Other nitrogen-heteroatom heterocyclic compounds in customs tariff 2933 99?
Classification of Other nitrogen-heteroatom heterocyclic compounds under CN code 2933 99 is based on chemical structure and functional groups. If in doubt, you can apply for Binding Tariff Information (BTI) from the national customs authority.
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